Acknowledgements This study was financially supported by Natural

Acknowledgements This study was financially supported by Natural Science Foundation of China under grant No. 11134006 and 51321091. Electronic supplementary material Additional file 1: Figure S1 LSCM images: (a) the products obtained from 2.5 mM CaCl2. (b) the products obtained from 10 mM CaCl2. Figure S1 shows the LSCM images of products grown in the mixing solutions with

CaCl2 concentrations of 2.5 mM (Figure S1a) and 10 mM (Figure S1b) respectively. The regular branched products could not be found in Figure S1, which means no such branched products are formed with CaCl2 concentration which is lower than 5 mM or higher ATR inhibitor than 7.5 mM. (JPEG 321 KB) References 1. Zhou GT, Guan YB, Yao QZ, Fu SQ: Biominetic mineralization of prismatic calcite mesocrystals: relevance to biomineralization. Chem Geol 2010, 279:63–72. 10.1016/j.chemgeo.2010.08.020CrossRef 2. Dong WY, Cheng HX, Yao Y, Zhou YF, 17DMAG concentration Tong GS, Yan DY, Lai YJ, Li W: Bioinspired synthesis of calcium carbonate hollow spheres with a nacre-type laminated microstructure. Langmuir 2011,27(1):366–370. 10.1021/la1034799CrossRef 3. Faatz M, Gröhn

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